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THERMODYNAMIC CALCULATIONS USING THE WATER TO COMBUSTIBLES RATIO
By PETER J. JAMES
A METHOD is presented that uses the water to combustibles ratio (W/C) introduced by
Frew and James to predict more accurately the thermodynamic outcomes from the use
of bagasse as a fuel. Key features of the model presented include: mass balance
equations; constant pressure specific heat equations of flue gas components; equations
for the change in enthalpy of flue gas components between a gas temperature T and an
ambient temperature To and in combustion air between To and a preheated air
temperature Ta; estimation of enthalpy losses in exhaust flue gas; spreadsheet modelling; discussion of ‘minor losses’; sugar cane technology applications: prediction of steam and power production capacity; calculation of adiabatic combustion temperature;
estimation of furnace combustion temperature; implications for boiler process control;
and design of dehydration plants. It is suggested that the model is more accurate than
methods generally used in the industry, based as it is on more detailed empirical specific
heat equations for flue gas component gases and on a more precise application of
different latent heat values (i) for water formed by combustion, and (ii) for water
present in the fuel.